
According to EPMA line mapping, (Mn,Fe)-carbide and (Mn,Fe)-phosphide coexist in the reduced particle. The current results could be applied for a promising treatment of dephosphorization of high phosphorus ores due to the low solubility of phosphorus in carbide. Keywords dephosphorization carbothermic reduction carburization manganese iron carbide
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In order to produce high-quality low-phosphorus low-carbon pure steel, The requirements of the content of ferromanganese P, C, S and other impurities in the steelmaking increasingly high. In addition to manganese-rich slag smelting process can remove phosphorus, in other ferromanganese smelting process, most of the raw materials in the ...
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High-phosphorus iron ore resource is considered a refractory iron ore because of its high-phosphorus content and complex ore phase structure. Therefore, the development of innovative technology to realize the efficient utilization of high-phosphorus iron ore resources is of theoretical and practical significance. Thus, a method for phosphorus removal by gasification in the hydrogen-rich ...
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say that the phosphorus removal has nearly the same effectiveness, it was even better in the case without CaF 2 2), see Table 1 . Fig.1 illustrates the relationships of Φp vs. fluxes consumption for both technologies. According to curves in Fig.1, it is showed that dephosphorization wasn´t affected by change in flux practice. Phosphorus
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Iron Ore Used to manufacture steels of various types. It's used in powdered iron, metallurgy products, magnets, high-frequency cores, auto parts, catalysts. Radioactive iron (iron 59) is used in medicine and in biochemical and metallurgical research. Iron blue is used in paints, inks, plastics, cosmetics and paper dyeing.
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The Influence of Sodium Oxide on the Distribution Behavior of Some Elements at the S-Furnace of the Mitsubishi Process, -- Effect of Temperature on Equilibrium Phase Relation and Liquidus of CaO-SiO2-Al2O3-FeOx System -- Viscosity Determination of the Freeze Slag in Reaction Shaft of Flash Smelting Furnace -- Effect of MgO Content on Melting Features and Viscosity of SiO2-CaO-MgO-Al2O3-FeO ...
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Cuyuna district (1) low-phosphorus ores, which are usually high in silica, and (2) high-phosphorus ores, which are as a rule moderately low' in silica. Low-phosphorus ores are commonly associated with cherty iron-bearing rocks and high-phosphorus ores with slaty iron-bearing rocks. This association, however, is not universal, and in some places ...
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Dephosphorization of high phosphorus iron ore: 12. Ferro Manganese production from lean grade Manganese ore: 13. Processing of Mineral & Metallurgical Wastes, and Flyash for their value addition: 14. Kinetics and thermodynamics study on reduction roasting of low and lean grade iron ores using fluidized bed roaster to maximise the recovery of ...
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The invention discloses a dephosphorization method for molten steel smelted by a medium-frequency induction furnace and belongs to the technical field of molten steel dephosphorization. According to the method, dephosphorization agents and fluxing agents are utilized to conduct dephosphorization on molten steel generated in the smelting process of the induction furnace, and the ...
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Oct 28, 2020The dephosphorization of a manganese oxide concentrate with an increased phosphorus content is experimentally studied by blowing a manganese-containing melt with carbon monoxide in the temperature range 1400-1560°C. The reaction of gaseous carbon monoxide with phosphorus oxide dissolved in a manganese-containing melt begins to develop.
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In general, dephosphorization slag can be divided into three major phases: a FeO-free phosphorus-rich phase (Ca 3 P 2 O 5 -Ca 2 SiO 4), a phosphorus-free manganese-enriched phase (mangano-wustite phase), and a phosphorus-free matrix phase (FeO-CaO-SiO 2) (Futatsuka et al., 2004, Kubo et al., 2008). Therefore, in principle, it is possible ...
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manganese. The phosphorus, in the manganese steel, can be found as solid solution inside the austenitic granule. When the phosphorus content increases over 0.12%, the free complex phosphide fixes at the austenitic granule margins, witch causes fragility both at low and at high temperatures.
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Russian manganese ores are characterized by an elevated phosphorus content (0.2-0.3%). Manganese concentrates obtained from such ores should be subjected to dephosphorization. Dephosphorization of manganese concentrates is currently carried out by a pyrometallurgical method.
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The high phosphorus content (0.35-0.50%) of high carbon ferromanganese originates from the manganese ores, majority of which contain significant amount (~0.2%) of phosphorus which is reduced almost completely during smelting reduction from its oxides. In India, low phosphorus ores are depleting fast and the high carbon ferromanganese pro-
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Feb 7, 2022Therefore, controlling the phosphorus content of Mn-Si alloy is of great significance for the quality of steel and the utilization of high-phosphorus manganese ore resources. Dephosphorization of Mn-Si alloys is usually performed using metallic calcium or Ca-based alloys in an argon atmosphere [ 7, 8, 9, 10 ].
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Made available by U.S. Department of Energy Office of Scientific and Technical Information ...
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In actual production, ores with low SiO 2 should be used for production convenience and lower energy consumption. On the other hand, the necessity for the dephosphorization operation can be considered depending on the phosphorus content in ore and the purity of pure iron required.
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Feb 02, 2019· Iron ores with phosphorus content lower than 0.07 Pmercially desired as they are suitable for use in iron production. As a consequence, a lot of research efforts have been focused on phosphorus removal from high phosphorus iron ore in a bid to reduce the P . Get a quote
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Finally, the relationship between manganese distribution Φ Mn and phosphorus distribution Φ P was investigated (see Fig.5). The Φ P represents quantitative parameter of dephosphorization, i.e. Φ P = (%P 2 O 5)/[%P]. Since phosphorus is very detrimental element for steel mechanical properties, Φ P values should be reached as high as possible.
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and β-Ca3(PO4)2 were prepared to represent the high phos-phorus manganese ores. MnO2 (Aldrich chemistry, >99% purity) was in size of greater than 63 μm and less than 250 μm, Fe2O3 was in size of 1 μm with 99.9 % purity. Because phosphorus exists mainly as apatite in manganese ores, β-Ca3(PO4)2 of 10 μm diameter was used as phospho-
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the ferromanganese alloy. Attempts have been made to remove phosphorus from manganese ores [1]. The majority of manganese ore deposits in central India have relatively high (> 0.3%) phosphorus levels. Since phosphorus is intimately associated with manganese [1], physical beneficiation is unsuitable and chemical beneficiation is necessary.
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ity as phosphorus can be in either PO4 -3 or P -3 form in slags depending on the existing oxygen partial pressure and temperature. Slag chemistry can also play a part, and for high chromium and manganese steels, due to the oxidation states of these alloying elements (Mn,Cr) in the slag, dephosphorization can be achieved by forming Ca 3 P 2
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PDF | On Jan 1, 1994, P N Chaudhary and others published Dephosphorization of Liquid Ferromanganese | Find, read and cite all the research you need on ResearchGate
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Research on Prediction Model for End Phosphorus Content during Dephosphorization by Multi-Refining Converter,TF713; Selection and Cultivation of Dephosphorus Strains on High Phosphorus Oolitic Hematite Ores,TD925.5; Yunnan the Xuanwei high phosphorus low manganese Refractory the the pyrolusite drop phosphorus mention manganese research,TD951
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The phosphorus partition between the unkilled liquid crude steel and the high basicity (CaO/SiO 2 = 4.2), basic oxygen furnace (BOF) slags with varying compositions of Al 2 O 3, TiO 2, and MnO is studied at temperatures 1600 and 1650 °C.The tests are conducted in both "slag-to-metal" and "metal-to-slag" directions and for durations of 30 and 60 min.
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Industrial Experimental Study on Dephosphorization Pretreatment ... Study on the Metallurgical Performances of Typical Manganese Ores.....345 Y. Zhang, Y. Zhang, Z. You, Y. Zhao, G. Li, and T. Jiang ... of Oolitic High-Phosphorus Iron Ore Fines.....427 H. Tang, W. Liu, L. Ma, and Z. Guo Modeling and CFD Simulations of Multiphase Melt Flows in ...
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At low basicity and low temperature, the dephosphorization behavior and phosphorus distribution ratio(LP) between slag and molten steel in the double slag and remaining slag process were studied with a 180 t basic oxygen furnace industrial experiment.The dephosphorization slags with different basicities were quantitatively analyzed.At the lower basicity range of 0.9-2.59, both LP and ...
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dephosphorization of hot metal to form a refined metal reduced in phosphorus components, and discharging said refined metal reduced in phosphorus components. In nature, metals are found in impure states called ores, often oxidized and mixed in with silicates of other metals.
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Removal of Phosphorus from High-Phosphorus Manganese Ores by Ammonia-Ammonium Carbonate Leaching Method December 2019 Metals - Open Access Metallurgy Journal 9(12):1354
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Phosphorus from high-phosphorus rhodochrosite affects electrolysis efficiency, leads to excess phosphorus in manganese metal during electrolytic manganese metal, and affects the steel productions performance and quality. Chemical precipitation technology in the presence of removing reagents was studied to remove phosphorus from acidic leach liquor that is produced by sulfuric acid leaching of ...
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Trans. Nonferrous Met. Soc. China 22(2012) 2806âˆ'2812 Mechanism of phosphorus removal in beneficiation of high phosphorous oolitic hematite by direct reduction roasting with dephosphorization agent XU Cheng-yan, SUN Ti-chang, KOU Jue, LI Yong-li, MO Xiao-lan, TANG Li-gang Key Laboratory of High-Efficient Mining and Safety of Metal Mines, Ministry of Education, University of Science and ...
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To improve the dephosphorization capacity of CaO-Al 2O 3-SiO 2-MnO based ferromanganese slag, this work attempts to introduce Ce 2O 3 as a strong phosphorus fixative into the slag, and the influence mecha-nism of Ce 2O 3 on the dephosphorization process is investigated by thermodynamic analysis, structural
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However, in the last decade, the iron ore price has risen by roughly 400% and lower cost iron sources generally have higher phosphorus content. In integrated steel plants, phosphorus removal usually takes place during the oxygen steelmaking process (OSM) but in Japan a intermediate step for hot metal dephosphorization is commonly used.
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enriched, dephosphorized high phosphorus ores 3) A way of making very fine concentrates sinterable in an ordinary ... partly in order to recover iron and manganese in the blast furnaces, with resulting increased concentration ... have done in Sweden on hot metal dephosphorization is largely based on earlier Japanese investigations.3-12) II. Ore ...
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high-phosphorus pellets,28-31) as well as the mechanism of phosphorus migration using pure reagents.32) In this work, the phosphorus migration among the gas, iron and gangue phases of medium-phosphorus magnetite ore during the carbothermic reduction process was quantitatively inves-tigated. This includes gasificating dephosphorization and
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The main dephosphorization product is Ca 3 P 2. Sufficient amount of Mn fine ore can effectively oxidize the phosphorus of reduction state to high valence states, further treat the RDP slag innocuously. After 30 days placement of disposed slags which were treated by sufficient manganese fine ore, the phosphorus content in the resultant is
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The development and utilization of mass transfer of phosphorus has been scarcely investigated. high-phosphorus iron ore resources may lead to higher Recently, Manning and Fruehan [11] investigated the rates phosphorus content in hot metal, which must correspond to of dephosphorization and rephosphorization of hot metal an increasing requirement ...
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D. K. Sahu, P. Prusti, S.K. Biswal, "Study the effect of blending of slimes with high-grade iron ore on reducibility, microstructure and swelling property of pellets", Abstract page 123, MPT-2016, Chennai; PROJECTS WORKED ON : "De-Phosphorization study of high-phosphorus iron ores", CSIR New Delhi
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This Special Issue, "Ironmaking and Steelmaking", released by the journal Metals, published 33 high quality articles from the international iron and steel community, covering the state-of-the-art of the ironmaking and steelmaking processes. This includes fundamental understanding, experimental investigation, pilot plant trials, industrial ...
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In these high phosphorus manganese ores, the phosphorus can be reduced to 0.15% or less by roasting the ores with 2-6 wt% NaCl at 750-800 °C followed by leaching in 0.5-0.75 M HNO 3 at 40-60 °C for a period of 15-20 min. Nwoye (2009) established a valid and precise model to evaluate the concentration of dissolved phosphorus during the leaching o...
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